Fiveable

🧪AP Chemistry Unit 3 Review

QR code for AP Chemistry practice questions

3.7 Solutions and Mixtures

🧪AP Chemistry
Unit 3 Review

3.7 Solutions and Mixtures

Written by the Fiveable Content Team • Last updated September 2025
Verified for the 2026 exam
Verified for the 2026 examWritten by the Fiveable Content Team • Last updated September 2025
🧪AP Chemistry
Unit & Topic Study Guides
Pep mascot

When taking a look at a chemical reaction, there are four phases of matter you may see after each compound: (s), (l), (g), or (aq). So far in this course, we've gone over solidsliquids, and gases quite a bit. Now, let's take a look at solutions since the aq stands for aqueous, or dissolved in water!

Review of Mixtures

In AP Chemistry, a mixture is typically referring to a heterogeneous mixture in which the macroscopic properties depend upon the location of particles in the mixture. An example of a hetereogeneous mixture would be something like soil, where you can actually see what is inside of the mixture, and macroscopic properties matter. 

Homogeneous mixtures exist as well, but they are uniform in composition and the macroscopic properties do not vary throughout the sample. If you took a look at a homogeneous mixture, like salt water, you would not be able to see the individual parts it is made up of.

This image may help you understand the difference between a heterogeneous and homogeneous mixture:

Pep mascot
more resources to help you study
Image Courtesy of Wikipedia

👉 Want a closer review of mixtures and examples of homogeneous and heterogenous mixtures? Review this unit one guide!

What are Solutions?

Solutions are homogeneous mixtures where the particles are evenly mixed and the solute is uniformly distributed within the solvent. The solute is the substance that is dissolved, while the solvent is the substance that does the dissolving.

Image Courtesy of Pinterest

Solutions can be made up of either solids, liquids, or gases. Here are some examples that may help you connect this chemistry material with your everyday life:

Examples of Solutions

When referring to a solid solution, you should think about alloys. Alloys can be formed when two or more elements, where at least one is a metal, are in their liquid form being mixed together. When this mixture cools, the alloy is created.

  • 🍳 Steel is a solid solution where the solute is carbon and the solvent is iron.
  • 🎺 Brass is a solid solution where the solute is zinc and the solvent is copper.

Liquid solutions are most likely what you think of when you see the word "solution." Here are a few:

  • 🧂Salt water where the solute is salt and the solvent is water.
  • 🍬 Sugar water where the solute is sugar and the solvent is water.
  • 🍋 Lemonade where the solutes are sugar and lemon juice and the solvent is water.

Gas solutions include:

  • 💨 Air all around you.
  • 🥤 Carbonated water where the solute is dissolved carbon dioxide and the solvent is water.

Within all of these examples, we can see that solutions form when one substance, the solute, disperses uniformly throughout another, the solvent. 

Interactions in Solutions

Solvation is the process of a solvent dissolving a solute to form a solution. It particularly describes the attractive interaction of solvent molecules with solute particles: the molecules of the solute become surrounded by molecules of the solvent. In other words, the solute particles are said to be "solvated."

When the solvent is water, this process and interaction is called hydration. When a substance is "hydrated," it becomes surrounded by water molecules.

In essence, solutions are a kind of mixture. While solids dissolved in liquids are probably the most common type of solution, it is not the only type, and this is important to keep in mind going forward.

Representing Solution Composition

When discussing solutions, we usually refer to concentration of a solute dissolved in a solvent. Concentration is a measure of the amount of solute that is dissolved in a given amount of solvent. There are tons of ways to calculate concentration, but the most important and most commonly used form of concentration is molarity. 

Molarity (M) is formally defined as the number of moles of a solute dissolved in one liter of solvent. Thus, the formula for molarity is M = moles of solute/liters of solution, hence the unit of molarity mol/L. For example, if we have a solution that contains 24 moles of HCl dissolved in 2L of water, the molarity is 24/2 = 12, or 12 M HCl as is commonly written. 

📝 Note: the numerator, moles of solute, only refers to the amount of solute. On the other hand, the denominator, volume of the solution, considers both the solute and the solvent, since they make up the solution together.

Other Ways to Represent Concentration

There are other ways of calculating concentration such as percent by mass and molality, but these won't be tested on the AP exam in May. Let's go over it anyways just in case you pursue chemistry past this course (otherwise you can completely skip this section)! 

Mass percent refers to the mass of solute / mass of solution x 100. When calculating mass percent, make sure to add the mass of the solute to the mass of the solvent to get the mass of solution.

Molality (m) = moles of solute / kilograms of solvent. Pay special attention to the units used to calculate molality! It is also good to keep in mind that the numerator refers only to the solute, while the denominator refers only to the solvent (not the solution, like the last two).

Forming a Solution

There are a few steps to forming a solution and each requires a certain amount of energy:

  1. Expand the solute (separate the solute into individual components)
  2. Expand the solvent (breaking IMFs to make room for the solute)
  3. Solute-Solvent Interactions (forming IMFs between the solute and the solvent) Sometimes, the first two steps can even be skipped.
Image Courtesy of Fiveable's Unit 3 Review

Diluting Solutions

Decreasing the concentration of a solute in a solution is referred to as diluting the solution. When we dilute a solution we have two options: remove some solute or add some solvent. Typically, removing solute is either completely impossible or difficult to control. Imagine having to accurately remove a certain mass of salt from a collection of salt water. It's essentially impossible! So, chemists often simply add solvent to the solution to get a lower molarity. Why does this work? Well, recall the definition of molarity: M = mol/L. 

If we lower the moles of solute, of course, molarity will decrease. Conversely, if the liters of solvent increases, molarity will also decrease! Thus, adding solvent is typically the easiest way to lower the concentration of a solution.

We can calculate exact volumes using the equation: M1V1 = M2V2, where M1 and V1 are the molarity and volume of the original solution and M2 and V2 refer to the molarity and volume of the diluted solution. 

Dilution is pretty important. Stock solutions used in lab are typically very concentrated since it is better to carry less material that has more substance. When its time to conduct an experiment, chemists dilute the stock solutions to the desired concentration.

How does dilution work?

M1V1 = M2V2 works because molarity * liters = mols (Moles/Liter * liter = moles) and since the number of moles remain constant throughout, M1V1 (the number of moles in the original solution) must necessarily equal M2V2 (the number of moles in the diluted solution). The only difference is in M1V1 and M2V2, molarity and volume are changing proportionally to each other.

You can just plug in the numbers and easily get any value you are solving for! 🥳

Frequently Asked Questions

What's the difference between a solution and a mixture?

A solution is a type of mixture that is homogeneous—its macroscopic properties are the same everywhere. It has a solvent (major component) and one or more solutes (minor components), and can be solid, liquid, or gas. A general mixture can be either homogeneous (a solution) or heterogeneous—in a heterogeneous mixture the composition and properties vary with location (particles or phases are visibly distinct). On the AP Chem CED terms: solutions = homogeneous mixture; heterogeneous mixture = nonuniform composition. AP problems often ask you to use concentration measures for solutions (molarity: M = n_solute / L_solution) or to count solute particles, volumes, or perform dilutions (LO 3.7.A). For quick review, see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and practice questions (https://library.fiveable.me/practice/ap-chemistry).

How do I calculate molarity step by step?

Molarity (M) = moles of solute ÷ liters of solution. Step-by-step: 1. Identify the solute and its mass or moles. If given grams, convert to moles using molar mass: n = mass (g) / Molar mass (g·mol⁻¹). 2. Make sure the solution volume is in liters. If given mL, divide by 1000: L = mL / 1000. 3. Apply the formula: M = n_solute / L_solution. Include units (mol·L⁻¹). Example: 5.00 g NaCl in 250.0 mL solution. - Molar mass NaCl = 58.44 g·mol⁻¹ → n = 5.00 / 58.44 = 0.0856 mol. - Volume = 250.0 mL = 0.2500 L. - M = 0.0856 mol / 0.2500 L = 0.342 M. On the AP exam you’ll be expected to show these algebraic steps, correct units, and significant figures (see CED Topic 3.7: M = n_solute / L_solution). For more worked examples and topic review check the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and practice problems (https://library.fiveable.me/practice/ap-chemistry).

What does homogeneous vs heterogeneous mixture mean?

A homogeneous mixture has the same macroscopic properties and composition everywhere in the sample—i.e., it’s uniform. Solutions are the classic example: salt dissolved in water, sugar in tea, or air (a gas solution). The AP CED even calls solutions “homogeneous mixtures” and emphasizes you’ll treat composition with measures like molarity M = n_solute / L_solution (Topic 3.7). A heterogeneous mixture has properties or composition that vary with location—you can see or separate different parts. Examples: oil + water layers, sand in water, or a salad dressing with suspended droplets. Colloids and suspensions fall between: particles may stay dispersed (colloid) or settle out (suspension). On the exam you should be able to identify which mixtures are uniform and apply concentration calculations for homogeneous solutions. For a focused review see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and practice problems (https://library.fiveable.me/practice/ap-chemistry).

I'm confused about the molarity formula - is it moles divided by liters of solution or solvent?

Molarity (M) is moles of solute divided by liters of solution—not liters of solvent. So M = n(solute) / L(solution), which means the final total volume after you’ve dissolved the solute. That’s the formula listed in the CED for Topic 3.7 (3.7.A.2). If you instead divide by kilograms of solvent you’re calculating molality (m), which is useful when temperature changes matter because molality doesn’t depend on volume. For lab prep: measure or make up to the final solution volume (e.g., dissolve solute, then dilute to the mark in a volumetric flask) to get the correct molarity. For more practice and review on solutions and concentration units, see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and extra problems at (https://library.fiveable.me/practice/ap-chemistry).

Why do we use molarity instead of other concentration units in chemistry lab?

Molarity (M = n_solute / L_solution) is the lab favorite because it links directly to the amounts of reactants you use in common experiments. You measure moles of solute (from mass) and then dilute to a known solution volume—that volume is easy to control with volumetric flasks and pipets, so making and diluting solutions (and doing titrations) is straightforward. Molarity plugs directly into stoichiometry and rate/equilibrium expressions (concentrations in mol·L⁻¹), which is exactly what AP problems ask you to calculate in Topic 3.7. Other units exist: molality (moles per kg solvent) is temperature-independent and better for some colligative-property work, and mole fraction is useful for gases—but they’re less convenient for routine lab prep and titration. Note: molarity depends on solution volume, so it can change slightly with temperature. For more practice and examples on preparing/diluting molar solutions see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and extra problems (https://library.fiveable.me/practice/ap-chemistry).

Can gases be solutions or just liquids?

Yes—solutions can be gases, not just liquids. The CED says a solution (a homogeneous mixture) can be a solid, liquid, or gas (3.7.A.1). Air is the classic gaseous solution: N2 is the major “solvent” and O2, CO2, and other gases are solutes. Gas mixtures are homogeneous when composition is uniform (contrast that with a heterogeneous mixture that varies by location). For AP work, remember molarity (M = n_solute / L_solution) is most often used for liquid solutions, since it uses solution volume, but for gases you often use mole fraction or partial pressure (Dalton’s law) to describe composition. Topic 3.7 questions on the exam can ask you to calculate number of solute particles, volume, or concentration—practice those in the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and more problems at (https://library.fiveable.me/practice/ap-chemistry).

What's the difference between solute and solvent in a solution?

Solute = the substance that gets dissolved (what’s present in smaller amount); solvent = the medium that does the dissolving (usually the larger amount). In a saltwater solution, NaCl is the solute and H2O is the solvent. In the AP CED language, a solution is a homogeneous mixture whose macroscopic properties don’t vary throughout the sample (3.7.A.1). Solutions can be solid, liquid, or gas (so “solute vs. solvent” applies to all phases). For concentration calculations you’ll often use molarity: M = n_solute / L_solution (3.7.A.2)—note that n refers to moles of solute and L is total solution volume. Remember: “solvent” is typically the majority component and determines the phase; “solute” changes properties like boiling point and freezing point (colligative effects). For quick review, check the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and practice problems (https://library.fiveable.me/practice/ap-chemistry).

How do I know if something is a homogeneous mixture or heterogeneous mixture just by looking at it?

Quick rule: a solution (homogeneous mixture) has the same macroscopic properties everywhere in the sample; a heterogeneous mixture’s properties depend on location (CED 3.7.A.1). Visual clues you can use: - Looks uniform/transparent at the scale you’re viewing it (e.g., salt dissolved in water) → likely homogeneous. - You can see different phases, chunks, layers, suspended particles, or cloudiness that scatters light → heterogeneous (colloid or suspension). - Tyndall effect (light beam visible through the sample) indicates particles large enough to scatter light → not a true solution. - If particles settle, can be filtered, or separate on standing → heterogeneous. - If unsure, sample different spots: if composition/appearance changes with location it’s heterogeneous; if it’s identical, it’s homogeneous. For lab confirmation: filtration/centrifugation, microscope, or letting it sit are practical tests. For more on AP-style definitions and examples, see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl). Practice problems are at (https://library.fiveable.me/practice/ap-chemistry).

If I have 2 moles of NaCl in 500 mL of solution what's the molarity?

Molarity M = moles of solute / liters of solution. You have 2.00 mol NaCl in 500 mL = 0.500 L, so M = 2.00 mol / 0.500 L = 4.00 M. Give the answer as 4.00 M (moles per liter). On the AP exam you should always write the formula M = nsolute / Lsolution, include units, and give an appropriate number of significant figures based on the data (here 3 sig figs). For a quick review of Topic 3.7 (solutions, molarity, and related calculations) see the Fiveable study guide for Unit 3 (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl). For extra practice problems, check Fiveable’s AP Chem practice set (https://library.fiveable.me/practice/ap-chemistry).

I don't understand why macroscopic properties don't vary in solutions - can someone explain this?

Think of a solution (a homogeneous mixture) as completely uniform at the scale you can see or measure without special separation. “Macroscopic properties don’t vary throughout the sample” means properties you can measure—concentration, color, density, refractive index, boiling point, etc.—are the same at every location in the container. That happens because the solute particles are evenly dispersed among solvent molecules; molecular motion (diffusion) and mixing produce a single phase with no separate regions of different composition. By contrast, a heterogeneous mixture has distinct regions (like oil + water) so macroscopic properties depend on where you measure. For AP Chem, use this idea when classifying mixtures and when calculating molarity or colligative effects: molarity (M = nsolute / Lsolution) describes a uniform concentration for the whole solution (CED 3.7.A.1–A.2). If you want a quick refresher or practice problems on solutions and mixtures, check the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and the AP practice bank (https://library.fiveable.me/practice/ap-chemistry).

What are some real world examples of heterogeneous mixtures?

Heterogeneous mixtures are ones whose macroscopic properties change with location (unlike solutions). Real-world examples you should know for Topic 3.7: oil + water (liquid-liquid immiscible layers), sand or gravel in water (suspension), salad dressing with herbs and oil, soil (solid particles + organic matter), concrete (cement + aggregate), granite (different mineral crystals), blood (cells + plasma—a suspension/colloid), smoke or dust in air (aerosol), and emulsions like mayonnaise (a dispersed phase in a continuous phase). Note: colloids (milk, fog) are a special type of heterogeneous mixture where particles are small enough to stay dispersed but not truly molecularly mixed. These examples connect to CED language: in heterogeneous mixtures the macroscopic properties depend on location. For extra review and AP-style practice on mixtures and concentrations (molarity, solute/solvent ideas), check the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and Unit 3 resources (https://library.fiveable.me/ap-chemistry/unit-3); practice questions are at (https://library.fiveable.me/practice/ap-chemistry).

How do I convert between different concentration units like molarity and molality?

Molarity (M) = moles solute per liter of solution. Molality (m) = moles solute per kilogram of solvent. To convert you need the solution’s density (or enough info to get mass of 1.00 L of solution) and the solute’s molar mass. Quick recipe (M → m): 1. Start with 1.00 L of solution. M tells you moles solute = M × 1.00 L. 2. Find mass of that solute: moles × molar mass (g). 3. Get mass of 1.00 L of solution from density (g/mL × 1000 mL). 4. Mass of solvent = mass of solution − mass of solute (convert to kg). 5. Molality = moles solute / kg solvent. Reverse (m → M): 1. Choose 1.00 kg solvent. Molality gives moles solute = m × 1.00 kg. 2. Find total mass = mass solvent + mass solute (g). Use density to get volume of solution. 3. Molarity = moles solute / volume (L). These steps tie directly to AP Topic 3.7 (M = n_solute / L_solution). For worked examples and practice, check the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and thousands of practice problems (https://library.fiveable.me/practice/ap-chemistry).

Why does the molarity equation use liters of solution and not liters of solvent?

Molarity is defined as moles of solute per liter of solution (M = n_solute / L_solution) because concentration describes how many solute particles are present in a given volume that you actually have to work with—the final homogeneous mixture. When you dissolve a solute the total volume usually changes (solute can expand or contract the solution), so using the solution’s volume gives the true particle density. If you used liters of solvent instead, you’d ignore that volume change and get the wrong concentration for reactions, equilibrium, or titrations (all tested in Topic 3.7 / LO 3.7.A). Molality (moles per kg solvent) is the alternative when you want a temperature-independent measure (mass doesn’t change with T), which is why colligative-property problems sometimes use molality. For review and problems on this, see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and more practice (https://library.fiveable.me/practice/ap-chemistry).

What happens to molarity when I dilute a solution with more water?

Molarity (M) goes down when you dilute a solution with more water. Molarity is defined as M = n_solute / L_solution, and dilution adds solvent without changing the number of moles of solute (n stays the same) while increasing the solution volume (L goes up), so M decreases. Use the dilution formula for calculations: M1·V1 = M2·V2. Example: 1.0 L of 2.0 M solution diluted to 2.5 L gives M2 = (2.0·1.0)/2.5 = 0.80 M. This is exactly the kind of calculation AP CED Topic 3.7 expects (Learning Objective 3.7.A). For a quick review, check the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and practice lots of dilution problems at Fiveable’s practice page (https://library.fiveable.me/practice/ap-chemistry).

Can you have a solid solution and how does that work?

Yes—a solution can be a solid. The CED even says solutions can be solids, liquids, or gases: what matters is homogeneity. In a solid solution one component (solute) is uniformly dispersed in another solid (solvent) so macroscopic properties don’t vary. Common examples are alloys: brass (Cu + Zn) and stainless steel (Fe + C + other metals) are substitutional or interstitial solid solutions (atoms replace host atoms or sit in gaps). In semiconductors, “doping” (tiny amounts of P or B in Si) is another solid-solution idea that changes properties. Composition for solids is usually given as percent by mass, mole fraction, or ppm rather than molarity. This topic ties to AP keywords (homogeneous mixture, solute, solvent, percent mass). For a focused review, see the Topic 3.7 study guide (https://library.fiveable.me/ap-chemistry/unit-3/solutions-mixtures/study-guide/lmjYxgiQN5yljSWPxWUl) and unit overview (https://library.fiveable.me/ap-chemistry/unit-3). For extra practice, check the practice problem bank (https://library.fiveable.me/practice/ap-chemistry).