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โ˜ข๏ธRadiochemistry Unit 2 Review

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2.4 Chart of nuclides and nuclear shell model

โ˜ข๏ธRadiochemistry
Unit 2 Review

2.4 Chart of nuclides and nuclear shell model

Written by the Fiveable Content Team โ€ข Last updated September 2025
Written by the Fiveable Content Team โ€ข Last updated September 2025
โ˜ข๏ธRadiochemistry
Unit & Topic Study Guides

The chart of nuclides is a powerful tool for visualizing nuclear properties. It plots protons vs neutrons, revealing stability trends and decay modes. This graphical representation helps us understand nuclear structure and behavior across different elements.

The nuclear shell model explains nuclear stability using energy levels for protons and neutrons. It identifies "magic numbers" that lead to extra-stable nuclei, similar to how electron shells determine chemical properties in atoms.

Chart of Nuclides

Representing Nuclides

  • Chart of nuclides graphically represents all known nuclides and their properties
  • Plots nuclides based on their proton number (Z) on the y-axis and neutron number (N) on the x-axis
  • Each square on the chart represents a unique nuclide with a specific number of protons and neutrons
  • Includes stable nuclides, unstable nuclides, and predicted nuclides that have not been observed experimentally

Segrรฉ Chart Characteristics

  • Segrรฉ chart is another name for the chart of nuclides named after Italian physicist Emilio Segrรฉ
  • Displays trends in nuclear stability across different isotopes and isotones
    • Isotopes have the same number of protons but different numbers of neutrons (horizontal direction on the chart)
    • Isotones have the same number of neutrons but different numbers of protons (vertical direction on the chart)
  • Color-codes nuclides based on their decay modes (alpha decay, beta decay, spontaneous fission)
  • Identifies "magic numbers" of protons and neutrons that correspond to increased nuclear stability

Nuclear Shell Model

Energy Levels in the Nucleus

  • Nuclear shell model describes the structure of the nucleus in terms of energy levels occupied by protons and neutrons
  • Similar to the electron shell model but applies to nucleons (protons and neutrons) instead of electrons
  • Each energy level corresponds to a specific number of protons or neutrons and has a defined energy and angular momentum
  • Nucleons fill energy levels from lowest to highest following the Pauli exclusion principle

Magic Numbers and Nuclear Stability

  • Certain numbers of protons or neutrons (2, 8, 20, 28, 50, 82, 126) result in increased nuclear stability
  • These "magic numbers" correspond to completed nuclear shells or subshells
  • Nuclides with magic numbers of protons or neutrons (doubly magic if both are magic numbers) have higher binding energies and greater stability compared to neighboring nuclides
  • Examples of doubly magic nuclides include $^{4}He$, $^{16}O$, $^{40}Ca$, and $^{208}Pb$

Nuclear Spin and Magnetic Moments

  • Nuclear spin is the intrinsic angular momentum of a nucleus determined by the spins of its constituent protons and neutrons
  • Nuclei with even numbers of protons and neutrons have integer spins (0, 1, 2, etc.), while those with odd numbers have half-integer spins (1/2, 3/2, 5/2, etc.)
  • Nuclear spin couples with the magnetic moments of protons and neutrons to give rise to the overall nuclear magnetic moment
  • Measuring nuclear spin and magnetic moments provides information about the distribution of protons and neutrons within the nucleus

Nuclear Moments

Nuclear Magnetic Moment

  • Nuclear magnetic moment arises from the intrinsic spins and orbital motions of protons and neutrons within the nucleus
  • Protons, being positively charged, contribute to the magnetic moment, while neutrons, despite being electrically neutral, also possess a smaller magnetic moment due to their internal quark structure
  • The total nuclear magnetic moment is a vector sum of the individual proton and neutron magnetic moments
  • Measured in units of nuclear magnetons ($\mu_N$) and can be positive or negative depending on the orientation of the net spin
  • Experimental techniques such as nuclear magnetic resonance (NMR) and Mรถssbauer spectroscopy can measure nuclear magnetic moments

Nuclear Quadrupole Moment

  • Nuclear quadrupole moment is a measure of the deviation of the nuclear charge distribution from spherical symmetry
  • Arises from the non-uniform distribution of protons within the nucleus
  • Nuclei with spin greater than 1/2 can possess a non-zero quadrupole moment
  • Positive quadrupole moments indicate a prolate (elongated) charge distribution, while negative values indicate an oblate (flattened) distribution
  • Measuring quadrupole moments provides information about the shape and deformation of nuclei
  • Experimental techniques such as nuclear quadrupole resonance (NQR) and hyperfine structure measurements can determine nuclear quadrupole moments