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๐ŸงถInorganic Chemistry I Unit 1 Review

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1.3 Periodic Table and Elemental Properties

๐ŸงถInorganic Chemistry I
Unit 1 Review

1.3 Periodic Table and Elemental Properties

Written by the Fiveable Content Team โ€ข Last updated September 2025
Written by the Fiveable Content Team โ€ข Last updated September 2025
๐ŸงถInorganic Chemistry I
Unit & Topic Study Guides

The periodic table organizes elements based on atomic structure and properties. It's divided into blocks, periods, and groups, each reflecting specific electron configurations and trends. Understanding these patterns helps predict chemical behavior and reactivity.

Elements are classified into main groups, transition metals, and inner transition series. This organization reveals similarities in properties, valence electrons, and chemical reactions. Recognizing these groupings is key to grasping elemental trends and periodic law.

Periodic Table Organization

Structure and Blocks of the Periodic Table

  • Periods run horizontally across the periodic table, representing increasing atomic number and electron shells
  • Groups form vertical columns, exhibiting similar chemical properties due to shared electron configurations
  • s-block elements occupy the first two groups, characterized by their outermost electrons in s orbitals
  • p-block elements comprise groups 13-18, featuring electrons in p orbitals as their highest energy level
  • d-block elements, known as transition metals, fill the central portion of the table with electrons in d orbitals
  • f-block elements, consisting of lanthanides and actinides, appear as two separate rows below the main table
  • Atomic radius generally decreases across periods and increases down groups
  • Ionization energy tends to increase across periods and decrease down groups
  • Electronegativity typically increases across periods and decreases down groups
  • Metallic character decreases across periods and increases down groups
  • Electron affinity generally increases across periods and decreases down groups
  • Shielding effect influences these trends by reducing the effective nuclear charge experienced by outer electrons

Element Classifications

Main Group Elements and Noble Gases

  • Main group elements encompass s-block and p-block elements, excluding noble gases
  • Alkali metals (Group 1) react vigorously with water, forming strong bases (sodium, potassium)
  • Alkaline earth metals (Group 2) form +2 ions and react with water to produce hydrogen gas (magnesium, calcium)
  • Halogens (Group 17) exist as diatomic molecules and are highly reactive non-metals (chlorine, bromine)
  • Noble gases (Group 18) exhibit extreme stability due to their full outer electron shells (helium, neon)
  • Chalcogens (Group 16) include important elements for biological processes (oxygen, sulfur)

Transition Metals, Lanthanides, and Actinides

  • Transition metals occupy the d-block, characterized by partially filled d orbitals
  • Transition metals often form colored compounds and exhibit variable oxidation states (copper, iron)
  • Many transition metals serve as catalysts in chemical reactions (platinum, palladium)
  • Lanthanides, part of the f-block, share similar chemical properties and are used in various technologies (neodymium in magnets)
  • Actinides, also in the f-block, include radioactive elements used in nuclear energy and weapons (uranium, plutonium)
  • Both lanthanides and actinides exhibit a gradual decrease in atomic radius across their respective series (lanthanide contraction)

Metalloids and Their Unique Properties

  • Metalloids possess properties intermediate between metals and non-metals
  • Located along the stair-step line on the periodic table, separating metals from non-metals
  • Metalloids can form alloys with metals and covalent bonds with non-metals
  • Semiconducting properties make metalloids crucial in electronics industry (silicon, germanium)
  • Boron, a metalloid, forms complex hydrides and is used in neutron-absorbing materials
  • Arsenic, another metalloid, finds applications in wood preservatives and electronic components